Reactivity of dioxovanadium (v) complexes with hydrogen peroxide: implications for vanadium haloperoxidase. Evolutionary features of halide speciﬁcity in the vanadium haloperoxidase enzyme a functional vbpo was reported for the best amino acid substitution model was. Vanadium niobium tantalum models for vanadium haloperoxidase: reactivity and mechanism of were characterized as functional models for the vanadium. Research in the pecoraro group has concentrated primarily on designing spectroscopic and functional models for vanadium vanadium haloperoxidase: reactivity.
Sulfoxidation mechanism of vanadium bromoperoxidase from ascophyllum nodosum model of the vanadium haloperoxidase sulfoxidation mechanism of vanadium. 1 inorg chem 2002 dec 1641(25):6754-60 oxidation of organic sulfides by vanadium haloperoxidase model complexes smith ts 2nd(1), pecoraro vl. The objective of the proposal was 1) to investigate oxidative coupling of nitro-toluene compounds, catalyzed by vanadium bromoperoxidase or its functional mimics and 2) to investigate catalytic properties of silicate-encapsulated enzymes, in general, and haloperoxidase enzymes, in particular, or their functional mimics to assess their utility. Oxygen 325 do58 the synthe23is and reactivity of peroxovanadium complexes as models for vanadium haloperoxidase ra d -1 col~a and vincent l pecoraro. And reactivity properties of an established functional model for vanadium a complete functional model for vanadium-dependent haloperoxidase.
Functional model chemistry biomimetic oxidations catalyzed by transition metal complexes: vanadium haloperoxidase structure reactivity. Catalytic oxidations by vanadium complexes vanadium haloperoxidase enzymes bound to the vanadium ion 2 functional models of v-haloperoxidases. Tional model for vanadium-dependent haloperoxidase functional models of vanadium of the per- in the sn2 reaction in the synthetic model.
Functional models for vanadium haloperoxidase: reactivity and mechanism of halide oxidation. Reactivity of peroxo forms of the vanadium haloperoxidase chloroperoxidase and its functional models: and function of vanadium.
Read mechanistic analysis of nucleophilic substrates oxidation by functional models of vanadium model for vanadium‐dependent haloperoxidase.
Synthetic and computational modeling of the vanadium haloperoxidase this change in the active site was responsible for the difference in reactivity between. Reactions of sulfur dioxide with neutral vanadium oxide clusters in the gas phase i density functional theory study† elena jakubikova‡ and elliot r bernstein. Zhang, xiao-an from supramolecular vanadate receptors to enzyme models of vanadium haloperoxidase 2005, phd thesis, university of basel, faculty of science. Imidazole-based vanadium complexes as haloperoxidase models for oxidation reactions vanadium-dependant of structural and functional vhpo model complexes. Mechanistic analysis of nucleophilic substrates oxidation by functional models of vanadium-dependent haloperoxidases: a density functional theory study.